What is zeise salt structure?

What is zeise salt structure?

Zeise’s salt, potassium trichloro(ethylene)platinate(II), is the chemical compound with the formula K[PtCl3(C2H4)]·H2O. The anion of this air-stable, yellow, coordination complex contains an η2-ethylene ligand. The anion features a platinum atom with a square planar geometry.

Is zeise salt pi bonded?

Zeise’s salt is a pi – bonded organometallic compound.

Why Zeise’s salt is diamagnetic?

In zeise’s salt Pt(II) is the central metal ion which is a square planar complex and the complex is diamagnetic. Central Pt 2+ ion coordinated with 3 Cl-ions and 1 ethene molecule in a square planar geometry while the 4 coplanar H’s are not coplanar with the 2 C’s.

What is zeise salt used for?

The researchers have found that the compound strongly inhibits cyclooxygenase (COX) enzymes, but it shows low cytotoxicity against cancer cells. The observation indicates that Zeise’s salt works differently than Peyrone’s salt, an analog better known as the potent chemotherapy drug cisplatin, PtCl2(NH3)2.

What is zeise salt and how it is prepared?

Zeise’s salt is the chemical compound with the formula K[PtCl3(C2H4)].H2O. The anion of this air-stable, yellow, coordination complex contains an η2-ethylene ligand. The complex is commonly prepared from K2[PtCl4] and ethylene in the presence of a catalytic amount of SnCl2.

What is zeise salt and ferrocene explain with structure?

This salt was prepared by Danish pharmacist Zeise in 1830 . It is one of the compound of transition metals which was prepared earlier. The plane of ethylene molecule and the C=C axis are perpendicular to the expected bond direction of the central atom. Ferrocene This is an orange-yellow compound.

Which of the following organometallic compounds are not pi bonded?

(CH3)4Sn.

Is Zeise’s salt is diamagnetic?

The incorrect statement about Zeise’s salt is (a)Zeise’s salt is diamagnetic (b) Oxidation state of Pt in Zeise’s salt is +2 (c)All the Pt-Cl bond length in Zeise’s salt are equal (d) C–C bond length of ethylene moiety in Zeise’s salt is longer than that of free ethylene molecule.

Which of the following is the incorrect statement about Zeise’s salt *?

Which of the following is the incorrect statement about Zeise’s salt? Explanation: C2F4 is a better π acceptor than C2H4.

What is zeise salt and ferrocene?

What is the basis of 18 electron rule?

18 electron rule : How to count electrons. The rule states that thermodynamically stable transition metal organometallic compounds. are formed when the sum of the metal d electrons and the electrons. conventionally considered as being supplied by the surrounding ligands equals 18.

What is zeise salt Class 12?

Zeise’s salt is an organometallic compound having the chemical formula K[PtCl3(C2H4)]. H2O, that is, potassium trichloro(ethylene)platinate (II). A. Zeise’s salt has a square planar geometry.

Which organometallic compound is sigma and pi bonded?

[Co(CO)5NH3]2+ is sigma and pi bonded organometallic compound.

What are the pi bonded organometallic compounds?

Pi bonds are the strong bonds that are formed from the sideways overlap of orbitals. Ferrocene consists of two pentadiene rings; each ring has two pi bonds and is considered as \[\pi \] bonded organometallic compounds.

What is the oxidation state of Pt in Zeise’s salt?

∴ oxidation number ofPt=+2.

Which one is correct for Zeise’s salt?

Zeise’s salt is a platinum complex containing 3 chloride ligands and 1 ethylene ligand. Its formula is K[PtCl3(C2H4)].